Dealuminated and Desilicated Natural Zeolite as a Catalyst for Hydrocracking of Used Cooking Oil into Biogasoline

Dealuminated and Desilicated Natural Zeolite as a Catalyst for Hydrocracking of Used Cooking Oil into Biogasoline

Authors

  • Karna Wijaya Universitas Gadjah Mada http://orcid.org/0000-0001-8155-0896
  • Susi Erfina Purba Universitas Gadjah Mada
  • Wega - Trisunaryanti Universitas Gadjah Mada
  • Remi Ayu Pratika Universitas Gadjah Mada

DOI:

https://doi.org/10.13171/mjc02101141493kw

Abstract

The modification of natural zeolite has been conducted by dealumination and desilication using HCl and NaOH treatments as a catalyst for hydrocracking of used cooking oil into biogasoline. This research aimed to study the effect of dealumination and desilication on the natural zeolite activity and selectivity of a hydrocracking process. A variety of catalysts was prepared by applying 3, 6, and 9 M HCl in the dealumination of natural zeolite to produce DNZ(3-1), DNZ(3-2) DNZ(3-3), DNZ(6-1), DNZ(6-2), DNZ(6-3), DNZ(9-1), DNZ(9-2), and     DNZ(9-3) catalysts and NaOH in the desilication of natural zeolite to obtain NZB catalyst. The results showed that the dealumination and the desilication treatments affected the liquid product conversion of used cooking oil from catalytic hydrocracking. The hydrocracking of used cooking oil with NZB catalyst produced the highest gasoline fuel conversion of 94.87%. 

 

 

Author Biographies

Karna Wijaya, Universitas Gadjah Mada

Karna Wijaya was born December 7, 1963 in Jakarta, got doktorandus degree from the Department of Chemistry of the Faculty of Mathematics and Natural Sciences, Gadjah Mada University in 1987, a Master of Engineering degree in Applied Chemistry from the School of Science and Engineering, Waseda University, Tokyo, Japan in 1993 and in 1999 received a Doctorate degree in Chemistry from the Technical University of Braunschweig, Germany. Served as a Professor since 2008. He currently teaches in the Department of Chemistry, Faculty of Mathematics and Natural Sciences, Gadjah Mada University, level under graduate (S-1) and postgraduates (S-2 and S-3). He teachs in the undergraduate degree some lectures, among others : Radiochemistry, Computational Chemistry, Solid State Chemistry, Quantum Chemistry, Chemical Kinetics, Chemical Equilibrium, Introduction to Materials Chemistry as well as Polymer Materials and Composites. In postgraduate, he taught Materials Science and Chemical Equilibrium. In addition, he also teaches undergraduate class of International Programme in the field of Radiochemistry, and Chemical Kinetics. At the level of the doctorate degree he taught Philosophy of Science and Review of Journal. In addition to teaching, Prof.Karna Wijaya also writes several scientific publications in international journals such as J.Natur. Forschung, Acta Crystalography, Asian Journal of Chemistry, International Journal of Applied Chemistry, Sustainable Environment Research and so forth. Some works of Prof.Karna Wijaya have already been patented and proposed to obtain patent rights. He is also actively involved as an author of several books published by LPPM and the Center for Energy Studies, GMU.

Susi Erfina Purba, Universitas Gadjah Mada

Department of Chemistry

 

Wega - Trisunaryanti, Universitas Gadjah Mada

Department of Chemistry

Remi Ayu Pratika, Universitas Gadjah Mada

Department of Chemistry

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Published

14-01-2021

Issue

Vol. 11 No. 1 (2021)

Section

Materials Chemistry

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