Synthesis of 8-Hydroxyquinoline/exchanged montmorillonite hybrids: Sorption, Luminescence and Thermal stability studies

Synthesis of 8-Hydroxyquinoline/exchanged montmorillonite hybrids: Sorption, Luminescence and Thermal stability studies

Authors

  • Besma Mellah Laboratory of Composite Materials and Clay Minerals, National Center of Researches in Material Sciences http://orcid.org/0000-0003-2658-027X
  • Thouraya Turki Laboratory of Composite Materials and Clay Minerals, National Center of Researches in Material Sciences
  • Wafa Chammam Laboratory of Composite Materials and Clay Minerals, National Center of Researches in Material Sciences
  • Ezzedine Srasra Laboratory of Composite Materials and Clay Minerals, National Center of Researches in Material Sciences

DOI:

https://doi.org/10.13171/mjc10502005201345bm

Abstract

Hybrids (H) prepared from 8-Hydroxyquinoline (8-HQ, "oxine") and exchanged montmorillonites (Na(I)-, Zn(II)- and Fe(III)-Mont) have been synthesized using solid-solid reactions at room temperature. The characterization of these hybrids by PPXRD has shown that the interlayer spaces swell (from 0.22 to 1.10 Å of d001 differences) after the inclusion of 8-HQ due to its complexation with the cations present. In the IR spectra, new bands corresponding to 8-HQ groups, appear in the regions 1244 - 1608 cm-1 and 574 - 826 cm-1. DSC measurement has shown the hybrids to be more stable than the precursor montmorillonites, 8-HQ and the simple metal oxinates. Zeta potential measurement on suspensions of the hybrids showed them to be negatively charged over the whole pH range (pH=2-10). As an application of our elaborated hybrids, sorption of the cationic dye methylene blue MB (CMB=200 mg.L-1) by the Na(I)-, Zn(II)- and Fe(III)-hybrids has been found to be rapid for the first two. At the same time, for the Fe(III) species, one month of sedimentation was required to adsorb 87 % of MB. The structural characterization of multi-hybrids MH (H+MB) by PXRD has shown a shift of d001 to higher values (Na-MH: 15.32 Å; Zn-MH: 16.61 Å; Fe-MH: 16.99 Å), signifying the intercalation of MB into interlayer spaces.

Author Biographies

Besma Mellah, Laboratory of Composite Materials and Clay Minerals, National Center of Researches in Material Sciences

Soliman, 8020

Thouraya Turki, Laboratory of Composite Materials and Clay Minerals, National Center of Researches in Material Sciences

Soliman, 8020

Wafa Chammam, Laboratory of Composite Materials and Clay Minerals, National Center of Researches in Material Sciences

Soliman, 8020

Ezzedine Srasra, Laboratory of Composite Materials and Clay Minerals, National Center of Researches in Material Sciences

Soliman, 8020

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Published

20-05-2020

Issue

Vol. 10 No. 5 (2020)

Section

Physical Chemistry

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