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Examining the effect of permanganate (KMnO4) on bamboo fiber (Bambusa vulgaris) reinforced with bio-resin natural honey (melitera) and pawpaw (Carica papaya) leaves extract

Ifeanyi John Obibuenyi, Okechukwu Dominic Onukwuli, Luvia Uche Ezeamaku, Ochiagha Innocent Eze

Abstract


Bamboo fibers are modified for improved interfacial bonding and reduction of moisture absorption. This is achievable through various treatments. The bamboo fiber's mechanical and chemical properties were examined with a Tensile machine and FTIR instrument. Natural fibers have many advantages over manufactured fibers like low density, low cost, biodegradability, poor compatibility between them and the matrix, relatively high moisture sorption, etc. The treatments are vital to modify the surface properties. For this, potassium permanganate (KMnO4) was used in this study. The Fourier transform Infra-red (FT-IR) analysis of untreated bamboo fiber showed the presence of the Hydrogen-bonded (O-H) stretch, H-C-H asymmetric and symmetric stretch, C-H stretch of C=O, C≡N stretch, N=O Bend, and C-O stretch. For the treated bamboo fiber, the analysis shows similar results. Similarly, results of reinforced bamboo fiber showed hydrogen-bonded O-H stretch, C-H stretch of C=O, C≡C stretch (C-O stretch), N=O stretch, and N-H bend. The treated Bamboo fiber was reinforced with a bio-resin (natural honey and pawpaw extract). Mechanical testing was done to get the tensile strength at increased concentration, and FT-IR was used to get the effects of chemical treatment on the fibers. Potassium permanganate treatment improved the properties with increased concentrations.


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M. Ramesh, L. Rajeshkumar, V. Bhuvaneshwari, Bamboo Fiber Reinforced Composite, Composites Science and Technology, 2021, 1-13. https://doi.org/10.1007/978-981-15-8489-3_1.

Y.J. Kim, J.K. Lim, A study on fatigue crack propagation mechanism of GFRP in synthetic seawater, KSME International Journal, 2001, 15, 1380-1385.

N. Chand, P.K. Rohatgi, Natural Fibres and Their Composites, Periodical Experts Book Agency, New Delhi, 1994.

P. J. H. Franco, A.V. Gonzalez, A study of the mechanical properties of short natural-fiber reinforced composites, Composites Part B: Engineering, 2005, 36, 597-608.

D. Huang, Y. Bian, Y. Zhou, B. Sheng, Experimental study on stress-strain relationships and failure mechanisms of parallel strand bamboo made from Phyllostachys, Construction and Building Materials, 2015, 77, 130-138.

P.V. Joseph, M.S. Rabello, L.H.C. Mattoso, K. Joseph, S. Thomas, Environmental effects on the degradation behaviour of sisal fibre reinforced polypropylene composites, Composites science and technology, 2002, 62, 1357-1372.

A.C.N. Singleton, C.A. Baillie, P.W.R. Beaumont, T. Peijs, On the mechanical properties, deformation and fracture of a natural fibre/recycled polymer composite, Composites Part B: Engineering, 2003, 34, 519-526.

A. Espert, F. Vilaplana, S. Karlsson, Comparison of water absorption in natural cellulosic fibres from wood and one-year crops in polypropylene composites and its influence on their mechanical properties, Composites Part A: Applied science and manufacturing, 2004, 35, 1267-1276.

Y. Li, Y. W. Mai, L. Ye, Sisal fibre and its composites: a review of recent developments, Composites science and technology, 2000, 60, 2037-2055.

D. Ray, B.K. Sarkar, S. Das, A.K. Rana, Dynamic mechanical and thermal analysis of vinyl ester-resin-matrix composites reinforced with untreated and alkali-treated jute fibres, Composites science and technology, 2002, 62, 911-917.

A.K. Bedzki, J. Gassan, Composites Reinforced with Cellulose Based Fibres, Progress in Polymer Science, 1999, 24, 221-274.

N. Banik, Manufacturing of bamboo composite in the industrial aspect, Materials Today: Proceedings, 2020, 26, 2875-2887.

M. Das, D. Chakraborty, Evaluation of improvement of physical and mechanical properties of bamboo fibers due to alkali treatment, Journal of Applied Polymer Science, 2008, 107, 522-527.

M. Das, D. Chakraborty, The Effect of alkalization and fiber loading on the mechanical properties of bamboo fiber composites, Part 1: Polyester resin matrix, Journal of Applied Polymer Science, 2009, 112, 489-495.

M. Das, D. Chakraborty, Effects of alkalization and fiber loading on the mechanical properties and morphology of bamboo fiber composites, Resol matrix, Journal of Applied Polymer Science, 2009, 112, 447-453.

A.E.C. Junior, A.C.H. Barreto, D.S. Rosa, F.J.N. Maia, D. Lomonaco, S.E. Mazzetto, Thermal and mechanical properties of bio-composites based on a cashew nut shell liquid matrix reinforced with bamboo fibers, Journal of Composite Materials, 2015, 49(18), 2203-2215.

K.J. Wong, B.F. Yousif, K.O. Low, Effects of alkali treatment on the interfacial adhesion of bamboo fibers, Journal of Materials, Design and Applications, 2010, 224(3), 139-148.

S. Qian, H. Wang, E. Zarei, K. Sheng, Effect of hydrothermal pretreatment on the properties of moso bamboo particles reinforced polyvinyl chloride composites, Composites: Part B, 2005, 82, 23-29.

F.D. Meng, Y.L. Yu, Y.M. Zhang, W.J. Yu, J.M. Gao, Surface chemical composition analysis of heat-treated bamboo, Applied Surface Science, 2006, 371, 383-390.

H. Kim, K. Okubo, T. Fujii, K. Takemura, Influence of fiber extraction and surface modification on mechanical properties of green composites with bamboo fiber, Journal of Adhesion Science and Technology, 2013, 27(12), 1348-1358.

T. Lu, M. Jiang, Z. Jiang, D. Hui, Z. Wang, Z. Zhou, Effect of surface modification of bamboo cellulose fiber on mechanical properties of cellulose/epoxy composites, Composites Part B: Engineering, 2013, 51, 28-34.

V. Kumar, R. Kumar, Dielectric and mechanical properties of alkali- and saline-treated bambu-epoxy nano-composites, Journal of Composite Materials, 2012, 46(24), 3089-3101.

J.T. Kang, S.H. Park, S.H. Kim, Improvement in the adhesion of bambu fibre reinforced polylactide composites, Journal of Composite Materials, 2014, 48(21), 2567-2577.

B. Sharma, A. van der Vegte, Engineered bamboo for structural applications, In: Nonconventional and vernacular construction materials. Woodhead Publishing, 2020, 597-623.

M. Jawaid, S.M. Sapuan, O.Y. Alothman, Expert material selection for manufacturing of green biocomposites, In: Green Biocomposites, Springer, Cham, 2017, 1-12.

P.E. Walter, T.O. Azeez, O.D. Onukwuli, C.U. Atuanya, Effects of chemical surface modification on Combretum dolichopetalum fibre for sustainable applications, Int. J. Eng. Sci. Res., 2016, 4, 81-96.

R.L. Banik, Bamboo, tropical, Forestry, 2015, 10(10), 91.

C. Saravanan, K. Prakash, Textiles—an overview, Feb 2008.

B.S. Furniss, A.J. Hannaford, P.W.G. Smith, A.R. Tatchell, Vogel’s Textbook of Practical Organic Chemistry, 5th edition, 2009.

D. Skoog, D.J. West, Holler, S. Crouch, Fundamentals of Analytical Chemistry, 8th edition, India, 2004.

R.N.O. Eddy, B.I. Dodo, E.D. Paul, Inhibitive and adsorption properties of ethanol extract of Hibiscus sabdariffa Calyx for the corrosion of mild steel in 0.1 M HCl, Green Chemistry, 2012.

E.M. Ezeh, O.D. Onukwuli, R.S. Odera, Novel Flame-Retarded Polyester Composites Using Cow Horn Ash Particles, International Journal of Advanced Manufacturing Technology, 2019.

E.M. Ezeh, O. Okeke, A.C. Ozuah, N. Bernard, Comparative Assessment of the Heavy and Trace Metal Levels in Honey Produced within Nsukka and Enugu Metropolis, Journal of Food and Public Health, 2018, 8, 42-46.

E.M. Ezeh, O.D. Onukwuli, V.I. Ugonabo, R.S. Odera, O. Okeke, Characterization of fire-Retardant properties of Cow Horn Ash Particles and Thermal Behavior of Polyester/Banana peduncle fibre/Cow horn ash particle hybrid composites, International Institute for Science, Technology and Education Academic Journal, 2020, 62, 37-46.

E.M. Ezeh, O.D. Onukwuli, Physiochemical Characterization of Cow Horn Ash and its effect as Filler material on the mechanical property of polyester – Banana fibre composite, World Journal of Engineering, 2020.




DOI: http://dx.doi.org/10.13171/mjc02212301652obibuenyi

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