Dear editor,I confirm that this work is original and has not been published elsewhere nor is it currently under consideration for publication elsewhere. Also I accepted, the article will not be published elsewhere in the same form, in any language

Effect of bismuth and bore content in glass system inhibitor on the corrosion behavior of mild steel in 1M hydrochloric acid solution

Azeddine Elbadaoui, Galai Mouhsine, Soumya Ferraa, Hanane Barebita, Mohammed Cherkaoui Cherkaoui, Taoufiq Guedira


The influence of (0.90-x) Bi2O3-xB2O3-0.10 (Ta2O5-Nb2O5) on the corrosion behavior of mild steel in 1M hydrochloric acid was studied. Electrochemical polarization and impedance spectroscopic methods measurements were used. The inhibition efficiency increases with S1 concentration to reach 79% at 150 ppm. Polarization curves show that our inhibitors. S1 is a cathodic inhibitor type. The increase in temperature leads to a decrease in the inhibition efficiency of the used inhibitor. The thermodynamic study showed that the film was formed at the steel surface by physisorption in the presence of inhibitor. Moreover, in this study, the results showed that the inhibition efficiencies depend on the B2O3 andBi2O3 content in the glass. it is observed that the value at 50% of B2O3 in the glass provided better protection than the other content.

Full Text:



- J. Zhang, J. Liu, W. Yu, Y. Yan, L. You, L. Liu, Corrosion. Sci., 2010, 52, 2059-2065.

- M. Iannuzzi, G.S. Frankel, Corrosion., 2007, 63, 672-688.

- A. Singh, S. K. Shukla, M. Singh, M. A. Quraishi, Mater. Chem. Phys., 2011, 129, 68-76

- S. K. Shukla, M. A.Quraishi, Mater.Chem.Phys., 2010, 120, 142-147.

- S. K. Shukla, A. K.Singh, I. Ahamad, M. A. Quraishi, Mater. Lett., 2009, 63, 819-822.

- S. K. Shukla, M. A. Quraishi, Corros. Sci., 2009, 51, 1007-1011.

- S. K. Shukla, M. A. Quraishi, R. Prakash, Corros. Sci., 2008, 50, 2867-2872.

- M. W. Ranney, Inhibitors Manufacture and Technology; 1976, Noyes Data Corp: NJ,

- F. Bentiss, M. Traisnel, H. Vezin, H.F. Hildebrand, M. Lagren, Corros.Sci., 2004, 46, 2781-2792

- R. A. Prabhu, T. V. Venkatesha, A. V. Shanbhag, B. M. Praveen, G. M. Kulkarni, R. G. Kalkhambkar, Mater. Chem. Phys., 2008, 108, 283.

- P. Lowmunkhong, D. Ungthararak, P. Sutthivaiyakit, Corros. Sci.,2010, 52, 30-36.

- F. Bentiss, C. Jama, B. Mernari, H. E. Attari, L. E. Kadi, M. Lebrini, M. Traisnel, M. Lagrenee, Corros. Sci., 2009, 51, 1628-1635.

- M. R. Ali, C.M. Mustafa, M. Habib, J. Sci. Res., 2009, 1, 82-91.

- M. Iannuzzi, G.S. Frankel, Corrosion, 2007, 63, 672-688.

- G.H. Nancollas, Corrosion, 1983, 39, 77-82.

- G.H. Nancollas, Corrosion, 1983, 39, 77-82.

- M. Belfaquir, Guedira, S. D. Elyoubi, J.L. Rehspringer, Synthèse et caractérisation des phases du système ternaire Bi2O3- P2O5- B2O3, Ann. Chim. SciencesMatériaux , 2005, 30, 27-35.

- M. Belfaquir, T.Guedira, S. D. Elyoubi, J.L. Rehspringer, Etude structurale des verres borate du systèmeBi2O3- P2O5- B2O3, Sciences Lib Editions Mersenne, 2013, 5.

- M. Belfaquir, T. Guedira, S. D. Elyoubi, J.L. Rehspringer, Etude vibrationnelle et électrique des verres de phosphates isolés dans le système Bi2O3- P2O5- B2O3, Sciences Lib Editions Mersenne, 2013, 5.

- 20. B.B. Meera, A.K. Sppd, N. Chandradhas, J. Ramakrishna, Journal of Non-Crystalline Solids, 1990, 12, 126, 224.

- A. Pawlicka, M. Atik, M.A. Aegerter . Thin Solid Films, 1997, 301, 236

- T. Armaroli, G. Busca, C. Carlini, M. Giuttari, A.M.R. Galletti, G. Sbrana, J. Mol. Catal. A,2000, 151, 233.

- M. Galai, J. choucri, Y. Hassani, H. Benqlilou, I. Mansouri, B. Ouaki, M. Ebn Touhami, C. Monticelli, F. Zucchi, Chemical Data Collections, 2019, 19, 100171.

- S.K. Shukla, M.A. Quraishi, Corros. Sci., 2009, doi:10.1016/j.corros.2009.05.020.

- M.G. Hosseini, M. Ehteshamzadeh, T. Shahrabi, Electrochem. Acta, 2007, 52, 3680-3685

- S. Murlidharan, K.L.N. Phani, S. Pitchumani, S. Ravichandran, J. Electrochem.Soc, 1995, 142, 1478-1483

- F. Bentiss, M. Traisnel, M. Lagrenee, Corros. Sci, 2000, 42, 127-146.

- B.G. Ateya, M.B.A. El-Khair, I.A. Abdel-Hamed, Corros. Sci, 1976, 15, 163- 169

- W. Li, Q. He, S. Zhang, C. Pei, B. Hou, J. Appl. Electrochem, 2008,38, 289-295.

- M. Galai, M. El Faydy, Y. El Kacimi, K. Dahmani, K. Alaoui, R. Touir, B. Lakhrissib and M. Ebn Touhami "Synthesis, Characterization and Anti-Corrosion Properties of Novel Quinolinol on C-steel in a Molar Hydrochloric Acid Solution." Portugaliae Electrochimica Acta, 2017, 35(4), 233-251.

- O.L. Riggs, Jr., Corrosion Inhibition, 1973, second ed., C.C. Nathan, Houston, TX.

- I. A. Ammar, F. M. El Khorafi, Werkst. Korros, 1973, 24, 702.

- K. Dahmani, M. Galai, M. Cherkaoui, A. El hasnaoui, A. El Hessni. J. Mater. Environ. Sci.2017, 8, 1676-1689.

- A. Popova, E. Sokolova, S. Raicheva, M. Christov, AC and DC study of the temperature effect on mild steel corrosion in acid media in the presence of benzimidazole derivatives." Corrosion Science,2003, 45, 33-58.

- T. Szauer, A. Brand, Adsorption of oleates of various amines on iron in acidic solution, Electrochim. Acta, 1981, 26, 1253-1256.

- H.Gerengi, K. Darowicki, G. Bereket, P. Slepski, Evaluation of corrosion inhibition of brass-118 in artificial seawater by benzotriazole using dynamic EIS, Corros. Sci, 2009, 51, 2573-2579.

- L. Saqalli, M. Galai, N. Gharda, M. Sahrane, R. Ghailane, M. Ebn Touhami, Y. Peres-lucchese, A. Souizi, N. Habbadi. Int. J. Electrochem. Sci., 2018,13, 5096-5119.

- A.K. Singh, S.K. Shukla, M. Singh, M.A. Quraishi, Inhibitive effect of ceftazidime on corrosion of mild steel in hydrochloric acid solution, Mater. Chem. Phys, 2011,129,68-76.

- M. Galai, M. Rbaa, Y. El Kacimi, M.Ouakki, N. Dkhirech, R. Touir, B. Lakhrissi and M. EbnTouhami, Anal. Bioanal. Electrochem, 2017, 9, 80-101

- A. Elbadaoui, M. Galai, M. Cherkaoui, T. Guedira. Preparation and characterization of a vitreous phase and application as a corrosion inhibitor in acidic medium. Der Pharma Chemica, 2016, 8, 214-221.

- M. Galai, M. El Gouri, O. Dagdag, Y. El Kacimi, A. Elharfi, M. Ebn Touhami. New Hexa Propylene Glycol Cyclotiphosphazene As Efficient Organic Inhibitor of Carbon Steel Corrosion in Hydrochloric Acid Medium. J. Mater. Environ. Sci, 2016, 7, 1562-1575.

- A. Majjane, D. Rair, A. Chahine, M. Et-tabirou, M. Ebn Touhami, R. Touir, Preparation and characterization of a new glass system inhibitor for mild steel corrosion in hydrochloric solution. Corrosion Science, 2012, 60, 98-103.



  • There are currently no refbacks.

Copyright (c) 2019 Mediterranean Journal of Chemistry