Cover Image

Effect of physical and chemical parameters on the β-Tricalcium phosphate synthesized by the wet chemical method

Asmaa Massit, Majda Fathi, Ahmed El Yacoubi, Abdelilah Kholtei, Brahim Chafik El Idrissi

Abstract


In this paper, the synthesis of nanosized powders β -Tricalcium phosphate β -Ca3(PO4)2 was studied by the wet chemical method at different values of reaction temperature, initial concentration of diammonium hydrogen phosphate (NH4)2HPO4, calcium nitrate tetrahydrate Ca(NO3)2·4H2O addition rate, pH of reaction and aging time. All these parameters have a great impact on the properties of the resulting β-TCP nano powders. Analysis results of morphology, structure of TCP powder from infrared (IR) spectra, X-ray diffraction (XRD) and transmission electron microscopy (TEM) indicated that the synthesized TCP powder had spherical crystal shape with crystallite size, calculated by XRD method, less than 60 nm, mono and biphasic structure composed of βTCP with pyrophosphate calcium or hydroxyapatite. The variation of the synthesis conditions did not affect the morphology, but it affect the size of crystallites and particles.

Full Text:

PDF

References


- A. Tevlek, P. Hosseinian, C. Ogutcu, M. Turk, H.M. Aydin, Bi-layered constructs of poly (glycerol-sebacate) tricalcium phosphate for bone-soft tissue interface applications, Mater. Sci. Eng. C, 2017, 72, 316-324.

- S. Hoover, S. Tarafder, A. Bandyopadhyay, S. Bose, Silver doped resorbable tricalcium phosphate scaffolds for bone graft applications, Mater. Sci. Eng. C, 2017, 79, 763-769.

- J. Park, S.J. Lee, H.H. Jo, J.H. Lee, W.D. Kim, J.Y. Lee, S.A. Park, Fabrication and characterization of 3D-printed bone-like -tricalcium phosphate/polycaprolactone scaffolds for dental tissue engineering, J. Ind. Eng. Chem., 2017, 46, 175-181.

- B.T. Smith, M. Santoro, E.C. Grosfeld, S.R. Shah, J.J.J.P. van den Beucken, J.A. Jansen, A.G. Mikos, Incorporation of fast dissolving glucose porogens into an injectable calcium phosphate cement for bone tissue engineering, Acta Biomater., 2017, 50, 68-77.

- M. Fathi, A. El Yacoubi, A. Massit, B. Chafik El Idrissi, Wet chemical method for preparing high purity β and α- tricalcium phosphate crystalline powders, IJSER, vol6, Iss6, 2015, 139-143.

Cen Y, Zhang TH, Gan CH, Yu G Wear studies of hydroxyapatite composite coating reinforced by carbon nanotubes. Carbon, 2007, 45, 998-1004.

Klein CPAT, Driessen AA, Groot K, Hoof A Biodegradation behavior of various calcium phosphate materials in bone tissue. J Biomed Mater Res, 1983, 17, 769-784.

- L. Sha, Y. Liu, Q. Zhang, M. Hu, and Y. Jiang, Microwave-assisted co-precipitation synthesis of high purity β-tricalcium phosphate crystalline powders, Materials Chemistry and Physics, vol. 129, no. 3, 2011, 1138-1141.

- Y. Pan, J.L. Huang, C.Y. Shao, Preparation of β-TCP with high thermal stability by solid reaction route, J. Mater.Sci., 2003, 38, 1049-1056.

- B. Chafik El Idrissi, K. Yamni, A. Yacoubi, A. Massit, A novel method to synthesize nanocrystalline hydroxyapatite: Characterization with x-ray diffraction and infrared spectroscopy, IOSR Journal of Applied ChemistryVol7, Issue 5 Ver. III, 2014, 107-112.

- S.C. Liou, S.Y. Chen, Transformation mechanism of different chemically precipitated apatitic precursors into β-tricalcium phosphate upon calcination, Biomaterials, 2002, 23, 4541-4547.

- A. Cuneyt Tas, F. Korkusuz, M. Timucin, N. Akkas, An Investigation of the Chemical Synthesis and

High-Temperature Sintering Behaviour of Calcium Hydroxyapatite (HA) and Tricalcium Phosphate (TCP) Bioceramics, J. Mater.Sci.Mater.Med., 1997, 8, 91-96.

- A. Farzadi , M. Solati-Hashjin, F. Bakhshi, A. Aminian, Synthesis and characterization of hydroxyapatite/b-tricalcium phosphate nanocomposites using microwave irradiation, Ceramics International, 2011, 37, 65-71.

- Li Shaa, YuyanLiub, Qing Zhanga, Min Hub, Yinshan Jiang, Microwave-assisted co-precipitation synthesis of high purity tricalcium phosphate crystalline powders, Materials Chem and Phys , 2011, 129, 1138-1141.

- M.B. Thürmer, C.E. Diehl, L.A.L. dos Santos, Calcium phosphate cements based on alpha-tricalcium phosphate obtained by wet method: synthesis and milling effects, Ceram. Int., 2016, 42, 18094-18099.

- C. Ruiz-Aguilar, et al., Characterization of -tricalcium phosphate powders synthesized by sol-gel and mechanosynthesis, Bol. Soc. Esp. Cerám. Vidr. 2018, 213-220.

- A. Destainville, E. Champion, D. Bernache-Assollant, E. Laborde, Synthesis, characterization and thermal behaviour of apatitic tricalcium phosphate, Materials Chemistry and Physics, 2003, 80, 269-277.

- S. Raynaud, E. Champion, D. Bernache-Assollant, J.-P. Laval, Determination of calcium/phosphate atomic ratio of calcium phosphate apatites using X-ray diffractometry, J.Am. Ceram. Soc., 2001, 84, 359-366.

- M. Santos, M. Oliveira, L. Souza, H. Mansur, W. Vasconcelos, Synthesis Control and Characterization of Hydroxyapatite Prepared by Wet Precipitation Process, Materials Research, 2004, 7, 625-630.

- R.G. Carrodeguas, A.H. De Aza, I. Garcia-Paez, S. De Aza, P. Pena, Revisiting the Phase-Equilibrium Diagram of the Ca3(PO4)2-CaMg(SiO3)2 System, J. Am. Ceram. Soc., 2010, 93, 561-569.

- K.P.Sanosh, Min-Cheol Chu, A.Balakrishnan, T.N.Kim, Seong-JaiCho, Sol-gel synthesis of pure nano-sized β-tricalcium phosphate crystalline powders, Current Applied Physics, 2010, 10, 68-71.

- B. Nasiri-Tabrizi, A. Fahami, Production of poorly crystalline tricalcium phosphate nanopowders using different mechanochemical reactions, J. Ind. Eng. Chem. 2014, 1236-1242.

- T. Nakano, A. Tokumura, Y. Umakoshi, Variation in crystallinity of hydroxyapatite and the related calcium phosphates by mechanical grinding and subsequent heat treatment, Metallurgical and Materials Transactions A, 2002, 33, 521-528.

- K.P. Sanosh, M.C. Chu, A. Balakrishnan, Y.J. Lee, T.N. Kim, S.J. Cho, Synthesis of nano-hydroxyapatite powder that simulates teeth particle morphology and composition, Current Applied Physics, 2009, 9, 1459-1462.

- A. Massit, A. El Yacoubi, A. Rezzouk, B. Chafik El Idrissi, Preparation of Tricalcium phosphate: effect of precursor addition rate on the microstructural properties, IJASTR, Issue 5 vol 4, 2015, 617-625.

- B. Nasiri-Tabrizi, A. Fahami, R.Ebrahimi-Kahrizsangi, Effect of milling parameters on the formation of nanocrystalline hydroxyapatite using different raw materials in, Ceramics International, 2013, 39, 5751-5763.




DOI: http://dx.doi.org/10.13171/mjc7310268-elidrissi

Refbacks

  • There are currently no refbacks.


Copyright (c) 2018 Mediterranean Journal of Chemistry