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Adsorption Study of Malachite Green Removal from Aqueous Solution Using Cu/M3+ (M3+=Al, Cr) Layered Double Hydroxide

Neza Rahayu Palapa, Risfidian Mohadi, Addy Rachmat, Aldes lesbani

Abstract


Layered double hydroxide (LDH) Cu/Al and Cu/Cr had been used as adsorbent of malachite green (MG) in aqueous solution. The properties of Cu/Al and Cu/Cr LDHs were analyzed by X-ray diffraction, surface area analysis (BET) and FTIR spectroscopy. Adsorption study of MG was achieved at pH 9. Adsorption of MG follows the pseudo-second-order kinetic model. Langmuir isotherm was suitable for adsorption of MG on both LDH with a maximum adsorption capacity of 59.52 mg/g. The thermodynamic study indicated that the adsorption process is physisorption, spontaneous, and endothermic process.  Adsorption of MG onto LDHs involve the acid-base interaction between adsorbent and adsorbate.


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- M. T. Yagub, T.K. Sen, S. Afroze, H.M. Ang, Dye and its removal from aqueous solution by adsorption: A review, Advances in Colloid and Interface Science, 2014, 209, 172–184.

- C. Wang, A. Yediler, D. Lienert, Z. Wang, A. Kettrup, Toxicity evaluation of reactive dyestuffs, auxiliaries and selected effluents in textile finishing industry to luminescent bacteria Vibrio fischeri, Chemosphere, 2002, 46, 339–344.

- A. Kausar, M. Iqbal, A. Javed, K. Aftab, Z.H. Nazli, H.N. Bhatti, S. Nouren, Dyes adsorption using clay and modified clay: A review, Journal of Molecular Liquids, 2018, 256, 395–407.

- G. Darmograi, B. Prelot, G. Layrac, D. Tichit,

G. Martin-Gassin, F. Salles, J. Zajac, Study of Adsorption and Intercalation of Orange-Type Dyes into Mg-Al Layered Double Hydroxide, J Phys Chem C, 2015, 119, 23388–23397.

- G. K. Sarma, S. Sen Gupta, K.G. Bhattacharyya, Removal of hazardous basic dyes from aqueous solution by adsorption onto kaolinite and acid-treated kaolinite: kinetics, isotherm and mechanistic study, SN Appl Sci., 2019, 1, 211.

- Momina, M. Rafatullah, S. Ismail, A. Ahmad, Optimization Study for the Desorption of Methylene Blue Dye from Clay Based Adsorbent Coating, Water, 2019, 11, 1304.

- A. Bennani Karim, B. Mounir, M. Hachkar,

M. Bakasse, A. Yaacoubi, Adsorption/desorption behavior of cationic dyes on Moroccan clay: Equilibrium and mechanism, J. Mater. Environ. Sci., 2017, 8, 1082–1096.

- M. Oktriyanti, N.R. Palapa, R. Mohadi, A. Lesbani, Modification Of Zn-Cr Layered Double Hydroxide With Keggin Ion, Indones. J. Environ. Manag. Sustain., 2019, 3, 93–99.

- Y. Xu, Z. Li, K. Su, T. Fan, L. Cao, Mussel-inspired modification of PPS membrane to separate and remove the dyes from the wastewater, Chem. Eng. J., 2018, 341, 371–382.

- A.S. Kalamdhad, J. Singh, K. Dhamodharan, Advances in Waste Management, Springer Singapore: Singapore, 2019. https://doi.org/10.1007/978-981-13-0215-2.

- X. Tao, Y. Han, C. Sun, L. Huang, D. Xu, Plasma modification of NiAlCe–LDH as improved photocatalyst for organic dye wastewater degradation, Appl. Clay Sci., 2019, 172, 75–79.

- N.R. Palapa, R. Mohadi, A. Lesbani, Adsorption of direct yellow dye from aqueous solution by Ni/Al and Zn/Al layered double hydroxides, Yogyakarta, Indonesia, 2018. https://doi.org/10.1063/1.5064978.

- T. Taher, D. Rohendi, R. Mohadi, A. Lesbani, Thermal and Acid Activation (TAA) of bentonite as an adsorbent for removal of methylene blue: A kinetics and thermodynamic study. Chiang Mai J. Sci., 2018, 45, 1770–1781.

- Z. Noorimotlagh, S.A. Mirzaee, S.S. Martinez, S. Alavi, M. Ahmadi, N. Jaafarzadeh, Adsorption of a textile dye in activated carbons prepared from DVD and CD wastes modified with multi-wall carbon nanotubes: Equilibrium isotherms, kinetics and thermodynamic study, Chemical Engineering Research and Design, 2019, 141, 290–301.

- R. Foroutan, R. Mohammadi, J. Razeghi, B. Ramavandi, Performance of algal activated carbon/Fe3O4 magnetic composite for cationic dyes removal from aqueous solutions, Algal Research, 2019, 40, 101509.

- K.-W. Jung, B.H. Choi, C.M. Dao, Y.J. Lee, J.W. Choi, K.-H. Ahn, S.-H. Lee, Aluminum carboxylate-based metal-organic frameworks for effective adsorption of anionic azo dyes from aqueous media, Journal of Industrial and Engineering Chemistry, 2018, 59, 149–159.

-U. Tezcan Un, F. Ates, Low-cost adsorbent prepared from poplar sawdust for removal of disperse orange 30 dye from aqueous solutions, Int J Environ Sci Technol, 2019, 16, 899–908.

-B.H. Hameed, M.I. El-Khaiary, Malachite green adsorption by rattan sawdust: Isotherm, kinetic and mechanism modeling, Journal of Hazardous Materials, 2008, 159, 574–579.

- O. Segun Esan, The Removal of Single and Binary Basic Dyes from Synthetic Wastewater Using Bentonite Clay Adsorbent. Am. J. Polym. Sci. Technol., 2019, 5, 16-28.

- T. Taher, D. Rohendi, R. Mohadi, A. Lesbani, Congo red dye removal from aqueous solution by acid-activated bentonite from sarolangun: kinetic, equilibrium, and thermodynamic studies, Arab Journal of Basic and Applied Sciences, 2019, 26, 125–136.

- N.R. Palapa, B. R. Rahayu, T. Taher, A. Lesbani, R. Mohadi, Kinetic Adsorption of Direct Yellow Onto Zn/Al and Zn/Fe Layered Double Hydroxides, sci technol indones, 2019, 4, 101-104.

- Z. Yang, F. Wang, C. Zhang, G. Zeng, X. Tan, Z. Yu, Y. Zhong, H. Wang, F. Cui, Utilization of LDH-based materials as potential adsorbents and photocatalysts for the decontamination of dyes wastewater: a review, RSC Adv, 2016, 6, 79415–79436.

- M.V. Bukhtiyarova, A review on effect of synthesis conditions on the formation of layered double hydroxides, Journal of Solid State Chemistry, 2019, 269, 494–506.

- D. Tichit, G. Layrac, C. Gérardin, Synthesis of layered double hydroxides through continuous flow processes: A review, Chemical Engineering Journal, 2019, 369, 302–332.

- J. Qu, L. Sha, C. Wu, Q. Zhang, Applications of Mechanochemically Prepared Layered Double Hydroxides as Adsorbents and Catalysts: A Mini-Review, Nanomaterials, 2019, 9, 80.

- H. Zhang, H. Chen, S. Azat, Z.A. Mansurov, X. Liu, J. Wang, X. Su, R. Wu, Super adsorption capability of rhombic dodecahedral Ca-Al layered double oxides for Congo red removal, Journal of Alloys and Compounds, 2018, 768, 572–581.

- F.Z. Mahjoubi, A. Elhalil, R. Elmoubarki, M. Sadiq, A. Khalidi, O. Cherkaoui, N. Barka, Performance of Zn‐, Mg‐ and Ni‐Al layered double hydroxides in treating industrial textile wastewater, Journal of Applied Surfaces and Interfaces, 2017, 2, 1‐11.

- S.A. Khan, S.B. Khan, A.M. Asiri, Layered double hydroxide of Cd-Al/C for the Mineralization and De-coloration of Dyes in Solar and Visible Light Exposure, Sci Rep., 2016, 6, 1-15.

- Z. Bai, C. Hu, H. Liu, J. Qu, Selective adsorption of fluoride from drinking water using NiAl-layered metal oxide film electrode, J. Colloid Interface Sci., 2019, 539, 146–151.

-M. Szabados, Z. Kónya, A. Kukovecz, P. Sipos, I. Pálinkó, Structural reconstruction of mechanochemically disordered CaFe-layered double hydroxide, Appl. Clay Sci., 2019, 174, 138–145.

-X. Duan, J. Lu, D.G. Evans, Assembly Chemistry of Anion-intercalated Layered Materials, Modern Inorganic Synthetic Chemistry, 2011, 375–404. https://doi.org/10.1016/B978-0-444-53599-3.10017-4.

- X.J. Liao, G.S. Chen, A hybrid hydrogel based on clay nanoplatelets and host-guest inclusion complexes, Chinese Chem. Lett., 2016, 27,

–587.

- C. Lei, M. Pi, P. Kuang, Y. Guo, F. Zhang, Organic dye removal from aqueous solutions by hierarchical calcined Ni-Fe layered double hydroxide: Isotherm, kinetic and mechanism studies, J. Colloid Interface Sci., 2017, 496, 158–166.

- F. Amor, A. Diouri, I. Ellouzi, F. Ouanji, M. Kacimi, High efficient photocatalytic activity of Zn-Al-Ti layered double hydroxides

nanocomposite, MATEC Web Conf., 2018, 149. https://doi.org/10.1051/matecconf/201814901087.

- A. Smalenskaite, L. Pavasaryte, T.C.K. Yang, A. Kareiva, Undoped and Eu3++ doped magnesium-aluminium layered double hydroxides: Peculiarities of intercalation of organic anions and investigation of luminescence properties, Materials, 2019, 12, 736.

- H. Wang, G. Fan, C. Zheng, X. Xiang, F. Li, Facile sodium alginate assisted assembly of Ni-Al layered double hydroxide nanostructures, Ind. Eng. Chem. Res., 2010, 49, 2759–2767.

- C.A. Antonyraj, P. Koilraj, S. Kannan, Synthesis of delaminated LDH: A facile two-step approach. Chem. Commun., 2010, 46, 1902.

- S. Berner, P. Araya, J. Govan, H. Palza, Cu/Al and Cu/Cr based layered double hydroxide nanoparticles as adsorption materials for water treatment, J. Ind. Eng. Chem., 2018, 59,

–140.

- E.S. Zhitova, S.V. Krivovichev, I. Pekov, H.C. Greenwell, Crystal chemistry of natural layered double hydroxides. 5. Single-crystal structure refinement of hydrotalcite, [Mg6Al2(OH)16](CO3)(H2O)4, Mineral. Mag., 2019, 83, 269–280.

- N. Mao, Y. Jiao, CuAl Hydrotalcite Formed CuAl-Mixed Metal Oxides for Photocatalytic Removal of Rhodamine B and Cr(VI), ChemistrySelect, 2018, 3, 12676–12681.

- K.M. Parida, L. Mohapatra, Carbonate intercalated Zn/Fe layered double hydroxide: A novel photocatalyst for the enhanced photodegradation of azo dyes, Chem. Eng. J., 2012, 179, 131–139.

- S. Das, S.K. Dash, K.Z. Parida, Kinetics, Isotherm, and Thermodynamic Study for Ultrafast Adsorption of Azo Dye by an Efficient Sorbent: Ternary Mg/(Al + Fe) Layered Double Hydroxides, ACS Omega, 2018, 3, 2532–2545.

- S.A. Haji Azaman, A. Afandi, B.H. Hameed, A.T. Mohd Din, Removal of malachite green from aqueous phase using coconut shell activated carbon: Adsorption, desorption, and reusability studies, J. Appl. Sci. Eng., 2018, 21, 317–330.

- Y.C. Lee, M.H.M. Amini, N.S. Sulaiman, M. Mazlan, J.G. Boon, Batch adsorption and isothermic studies of malachite green dye adsorption using leucaena leucocephala biomass as a potential adsorbent in water treatment, Songklanakarin J. Sci. Technol., 2018, 40, 563–569.

- M. Rajabi, Adsorption of malachite green from aqueous solution by carboxylate group functionalized multi-walled carbon nanotubes: Determination of equilibrium and kinetics parameters, J. Ind. Eng. Chem., 2016, 34, 130–138.

- F. Kovanda, Layered Double Hydroxides Intercalated With Organic Anions and. Acta Geodyn, Geomater, 2009, 6, 111–119.

- E. Sharifpour, E. Alipanahpour Dil, A. Asfaram, M. Ghaedi, A. Goudarzi, Optimizing adsorptive removal of malachite green and methyl orange dyes from simulated wastewater by Mn-doped CuO-Nanoparticles loaded on activated carbon using CCD-RSM: Mechanism, regeneration, isotherm, kinetic, and thermodynamic studies, Appl. Organomet. Chem., 2019, 33, 1–14.

- G. George, M.P. Saravanakumar, Facile synthesis of carbon-coated layered double hydroxide and its comparative characterisation with Zn-Al LDH: application on crystal violet and malachite green dye adsorption-isotherm, kinetics and Box-Behnken design, Environ. Sci. Pollut. Res. Int., 2018, 25, 30236–30254.

- P. Chakraborty, R. Nagarajan, Efficient adsorption of malachite green and Congo red dyes by the surfactant (DS) intercalated layered hydroxide containing Zn2+ and Y3+-ions, Appl. Clay Sci., 2015, 118, 308–315.

- N.R. Palapa, T. Taher, R. Mohadi, M Said, Synthesis of Ni/Al Layered Double Hydroxides (LDHs) for Adsorption of Malachite Green and Direct Yellow Dyes from Solutions : Kinetic and Thermodynamic, 2018, 226, 020033.

- S. Mukherjee, A. Kumar, M. Zaworotko, Metal-organic framework based carbon capture and purification technologies for a clean environment, J. environment Republic of Ireland, 2019. https://doi.org/10.1016/B978-0-12-814633-0.00003-X.

- Y. Lu, B. Jiang, L. Fang, F. Ling, J. Gao, F. Wu, X. Zhang, High-performance NiFe layered double hydroxide for methyl orange dye and Cr(VI) adsorption, Chemosphere, 2016, 152, 415–422.

- M. Greluk, Z. Hubicki, Efficient removal of Acid Orange 7 dye from water using the strongly basic anion exchange resin Amberlite IRA-958, Desalination, 2011, 278, 219–226.

- O. León, A.M. Bonilla, D. Soto, D. Pérez, M. Rangel, M. Clina, M.F. Garcia, Removal of anionic and cationic dyes with bioadsorbent oxidized chitosans, Carbohydr. Polym., 2018, 194, 375–383.




DOI: http://dx.doi.org/10.13171/mjc10102001261236al

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